in this paper, we initiated two methods which monomer or polymer are charged in the pores of mcm-41 to prepare the polymer / mcm-41 nanocomposites, utilizing the marked " shape-selective " " modificable pore walls " and " less stabilization " properties of mcm-41 . the engraftion between the polymer and mesoporous molecular sieves is realized in our research 本論文首次利用介孔分子篩的擇型約束、孔壁可修飾、介穩(wěn)相狀態(tài)等特點(diǎn),通過穿孔原位聚合和聚合物熔體穿孔改性兩種模式,制備聚合物基納米復(fù)合材料,實(shí)現(xiàn)聚合物和介孔分子篩的嫁接。