The anodic overpotential and reaction - rate distributions throughout the catalyst layer are affected by increasing the protonic conductivity to 增加電解質(zhì)的傳導(dǎo)率有助于陽(yáng)極催化層過電位和反應(yīng)速率均勻分布,從而提高dmfc的性能。
Also , the steady mass specific peak current of oxygen reduction methanol on this modified platinum was 20 % more than that on the non - modified platinum , the overpotential of ox Vulcanxc 72活性碳粉的引入使抗co中毒的性能又得到了進(jìn)一步提高,單位質(zhì)量的pt的氧還原峰電流又進(jìn)一步增大。
The tffa model calculation has been carried out to investigate the effects of structural parameters of the afc cathode and pemfc cathode on the electrode performance , which is respectively represented by the curve of cathode overpotential versus current density and the curve of cathode potential versus current density 本文運(yùn)用tffa模型分別考察了afc陰極過電位?電流密度的曲線和pemfc陰極伏安曲線受陰極結(jié)構(gòu)參數(shù)變化的影響程度。
The result shows that with the addition of rare earth elements , ultrasonic irradiation and magnetic field , the chemical component , surface configuration , microstructure and properties of electroless co - ni - b and co - fe - b alloy changes remarkably . such kind of change can be described as the followings . firstly the depositing speed of electroless alloy bath is raised while the polarizability and cathodic overpotential are reduced ; secondly the surface quality of the alloy coating and adhesion of the coating and matrix are improved ; thirdly in the coatings the content of the elements in the transient group increases , but the content of cobalt decreased ; fourthly the amorphous structure is transformed to microcrystal structure and polycrystal structure ; fifthly the microhardness and wear resistance of the coating are enhanced ; sixthly coercitive force is reduced , and magnetoconductivity of the coating is increased ; lastly the magnetic intensity of the coating increases with the addition of energy and light rare earth elements such as ce , la and decreases with the addition of heavy rare earth elements such as y . on the other side , when the alloy coatings passes through the heat treatment under the temperature of 250 or 500 , their properties will change 結(jié)果顯示化學(xué)沉積co - ni - b 、 co - fe - b工藝在稀土元素( ce 、 la 、 y 、 dy ) 、能量(超聲波、磁場(chǎng))介入后,沉積過程、合金成分、鍍層形貌結(jié)構(gòu)和性能都有顯著變化,表現(xiàn)在:鍍液的陰極極化過電位和極化度降低,沉積速度提高;鍍層的結(jié)合力、表面質(zhì)量改善;鍍層中過渡族元素的含量增加,輕元素硼的含量降低,同時(shí)證實(shí)了稀土元素與過渡族元素共沉積的可能性;鍍層的顯微結(jié)構(gòu)由非晶態(tài)向微晶和多晶態(tài)轉(zhuǎn)變;鍍層的顯微硬度與耐磨性提高,力學(xué)性能優(yōu)化;鍍層的矯頑力降低;磁導(dǎo)率提高;鍍層的磁化強(qiáng)度在能量(超聲波、磁場(chǎng))和輕稀土元素ce 、 la介入后提高,重稀土元素y介入后降低。
Mol l , artemisinin can be reduced via the hemin - catalysis and its original cathodic peak at - 1 . 08v completely disappeared . the cathodic overpotential of artemisinin is decreased ca . 600mv . this process is verified by the fact that complex edta - fe can also promote the artemisinin reduction with decreasing the cathodic overpotential of artemisinin for 590mv . these results show that the reduction of artemisinin at the glassy carbon electrode is a catalytic process with the aids of hemin . hemin can greatly decrease the cathodic activation energy of the reduction of artemisinin and promote the decomposition of artemisinin Mol l氯化血紅素存在下,青蒿素仍可被催化還原,陰極過電位降低了600mv 。配合物edta - fe具有類似氯化血紅素的催化性質(zhì),它降低了qhs陰極過電位590mv 。在這個(gè)體系中,青蒿素在碳電極上的還原是一個(gè)借助于氯化血紅素催化的還原過程,氯化血紅素的存在降低了青蒿素還原活化能,促進(jìn)了青蒿素的分解。
Overpotential is an electrochemical term which refers to the potential difference (voltage) between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed.Bard, A.