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pseudorotation造句

"pseudorotation"是什么意思   

例句與造句

  1. Disphenoidal molecules, like trigonal bipyramidal ones, are subject to Berry pseudorotation.
  2. Pseudorotation also occurs in square pyramidal molecules.
  3. Berry pseudorotation influences the 19 F NMR spectrum of PF 5 since NMR spectroscopy operates on a millisecond timescale.
  4. It is a fluxional molecule in which the axial ( ax ) and equatorial ( eq ) fluorine atoms interchange positions by the Berry pseudorotation mechanism.
  5. The apparent equivalency arises from the low barrier for pseudorotation via the Berry mechanism, by which the axial and equatorial fluorine atoms rapidly exchange positions.
  6. It's difficult to find pseudorotation in a sentence. 用pseudorotation造句挺難的
  7. Experimentally, instead of direct measurement of the energy difference, which is usually difficult to measure, the relative energy barriers for pseudorotation of isomers are used for determination of the apicophilicity scale.
  8. The two hydrogen atoms in the H 2 molecule can continuously exchange positions with the three hydrogen atoms in the CH 3 + ion ( a conformation change called pseudorotation, specifically the Berry mechanism ).
  9. These results were used to establish a mechanism for this isomerization in square planar d 8 palladium species that consists of solvent or phosphine association followed by pseudorotation and subsequent dissociation of the solvent or phosphine.
  10. In particular they reveal that the barrier to pseudorotation almost vanishes ( the system is highly  fluxional ) which can be attributed to the fact that the 2nd-order coupling terms vanish by symmetry and the leading higher-order terms are of 4th order.
  11. In particular they reveal that the barrier to pseudorotation almost vanishes ( the system is highly " fluxional " ) which can be attributed to the fact that the 2nd-order coupling terms vanish by symmetry and the leading higher-order terms are of 4th order.

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